Distribution of platinum-group elements in the Platreef at Overysel,northern Bushveld Complex: a combined PGM and LA-ICP-MS study   总被引：1，自引：0，他引：1  

D. A. Holwell  I. McDonald 《Contributions to Mineralogy and Petrology》2007,154(2):171-190

Detailed mineralogical and laser ablation-inductively coupled plasma-mass spectrometry studies have revealed the physical manifestation of the platinum-group elements (PGE) within the Platreef at Overysel, northern Bushveld Complex, South Africa. The PGE in the Platreef were originally concentrated in an immiscible sulfide liquid along with semi-metals such as Bi and Te. As the sulfide liquid began to crystallize, virtually all the Os, Ir, Ru and Rh partitioned into monosulfide solid solution (mss), which on further cooling, exsolved to form pyrrhotite and pentlandite with Os, Ir and Ru remaining in solid solution in both phases with Rh prefentially partitioning into pentlandite. Platinum, some Pd and Au were concentrated in the residual sulfide liquid after mss crystallization, and were then concentrated in an immiscible late stage melt along with semi metals, which was expelled to the grain boundaries during crystallization of intermediate solid solution (iss) to form Pt and Pd tellurides and electrum around the margins of the sulfide grains. Tiny droplets of this melt trapped in the crystallizing mss and iss cooled to form Pt–Bi–Te microinclusions in all sulfide phases, whilst the excess Pd was accommodated in solid solution in pentlandite. Minor redistribution and recrystallization by hydrothermal fluids occurred around xenoliths and at the very base of the mineralized zone within the footwall, however, the overall lack of secondary alteration coupled with the volatile-poor nature of the gneissic footwall have allowed the preservation of what may be the most ‘primary’ style of Platreef mineralization. The lack of PGM inclusions within early liquidus phases suggests very early sulfur saturation in the Platreef, lending support to theories involving S saturation occurring prior to intrusion of the Platreef, possibly within a staging chamber.  相似文献   

粘土矿物在过去环境变化研究中的应用   总被引：9，自引：4，他引：9       下载免费PDF全文

隆浩  王晨华  刘勇平  马海州 《盐湖研究》2007,15(2):21-25,29

粘土矿物是一种广泛分布于地表的沉积物,其组合及含量的变化记录了源区过去气候环境变化的信息。因此,可以根据粘土矿物的含量和组合变化等信息推知其形成时期的气候环境,重建古环境,揭示气候环境演变的规律。粘土矿物是一种研究古环境演化重要的代用指标,在过去气候环境变化研究中有广阔的应用前景。  相似文献   

Late Quaternary clay minerals off Middle Vietnam in the western South China Sea: Implications for source analysis and East Asian monsoon evolution     

Christophe COLIN 《中国科学D辑(英文版)》2007,50(11):1674-1684

High-resolution clay mineral records combined with oxygen isotopic stratigraphy over the past 450 ka during late Quaternary from Core MD05-2901 off Middle Vietnam in the western South China Sea are re-ported to reconstruct a history of East Asian monsoon evolution. Variations in Illite, chlorite, and kaolinite contents indicate a strong glacial-interglacial cyclicity, while changes in smectite content present a higher frequency cyclicity. The provenance analysis indicates a mixture of individual clay minerals from various sources surrounding the South China Sea. Smectite derived mainly from the Sunda shelf and its major source area of the Indonesian islands. Illite and chlorite originated mainly from the Mekong and Red rivers. Kaolinite was provided mainly by the Pearl River. Spectral analysis of the kaolin-ite/(illite chlorite) ratio displays a strong eccentricity period of 100 ka, implying the ice sheet-forced win-ter monsoon evolution; whereas higher frequency changes in the smectite content show an ice sheet-forced obliquity period of 41 ka, and precession periods of 23 and 19 ka and a semi-precession period of 13 ka as well, implying the tropical-forced summer monsoon evolution. The winter monsoon evolution is generally in coherence with the glacial-interglacial cyclicity, with intensified winter monsoon winds during glacials and weakened winter monsoon winds during interglacials; whereas the summer monsoon evolution provides an almost linear response to the summer insolation of low latitude in the Northern Hemisphere, with strengthened summer monsoon during higher insolation and weakened summer monsoon during lower insolation. The result suggests that the high-latitude ice sheet and low-latitude tropical factor could drive the late Quaternary evolution of East Asian winter and summer monsoons, respectively, implying their diplex and self-contained forcing mechanism.  相似文献   

利用非金属矿制备白炭黑现状及发展前景   总被引：8，自引：0，他引：8  

周光  王廷吉 《华东地质学院学报》2001,24(4):298-302

简术了白炭黑的用途和制备方法，综述了利用非金属矿制备白炭黑的方法和技术现状，对充分利用非金属矿制备白炭黑提供思路并展望其发展前景。  相似文献   

环境矿物材料基本性能：无机界矿物天然自净化功能   总被引：53，自引：23，他引：53       下载免费PDF全文

鲁安怀 《岩石矿物学杂志》2001,20(4):371-381

重点阐述环境矿物材料基本性能，包括矿物表面吸附、孔道过滤、结构调整、离子交换、化学活性、物理效应、纳米效应及与生物交互作用等，旨在发掘、凝炼并新提出物理方法和化学方法之后与有机界生物同效的无机界矿物天然自净化功能的基础理论与应用方法，以发展和完善无机矿物与有机生物所共同构筑的自然界中存在的天然自净化系统，并就目前笔者在黄铁矿、锰钾矿、金红石、蛭石、蒙脱石、苋铁铁钒等天然矿物方面已经完成和正在开展的一系列环境矿物材料研究工作进行了举例说明。  相似文献   

The heat capacity of two natural chlorite group minerals derived from differential scanning calorimetry     

C. Bertoldi  A. Benisek  L. Cemic✓  E. Dachs 《Physics and Chemistry of Minerals》2001,28(5):332-336

The heat capacity of natural chamosite (X_Fe=0.889) and clinochlore (X_Fe=0.116) were measured by differential scanning calorimetry (DSC). The samples were characterised by X-ray diffraction, microprobe analysis and Mössbauer spectroscopy. DSC measurements between 143 and 623?K were made following the procedure of Bosenick et?al. (1996). The fitted data for natural chamosite (CA) in J?mol^?1?K^?1 give: C _p,CA = 1224.3–10.685?×?10³?×?T ^??0.5???6.4389?× 10⁶?×T ^??2?+?8.0279?×?10⁸?×?T ^??3 and for the natural clinochlore (CE): C _p,CE = 1200.5–10.908?×?10³?×T ^??0.5?? 5.6941?×?10⁶?×?T ^??2?+?7.1166?×?10⁸?×?T ^??3. The corrected C _p-polynomial for pure end-member chamosite (Fe₅Al)[Si₃AlO₁₀](OH)₈ is C _p,CAcor = 1248.3–11.116?× 10³?×?T ^??0.5???5.1623?×?10⁶?×?T ^??2?+?7.1867?×?10⁸×T ^??3 and the corrected C _p-polynomial for pure end-member clinochlore (Mg₅Al)[Si₃AlO₁₀](OH)₈ is C _p,CEcor = 1191.3–10.665?×?10³?×?T ^??0.5???6.5136?×?10⁶?×?T ^??2?+ 7.7206?×?10⁸?×?T ^??3. The corrected C _p-polynomial for clinochlore is in excellent agreement with that in the internally consistent data sets of Berman (1988) and Holland and Powell (1998). The derived C _p-polynomial for chamosite (C _p,CAcor) leads to a 4.4% higher heat capacity, at 300?K, compared to that estimated by Holland and Powell (1998) based on a summation method. The corrected C _p-polynomial (C _p,CAcor) is, however, in excellent agreement with the computed C _p-polynomial given by Saccocia and Seyfried (1993), thus supporting the reliability of Berman and Brown's (1985) estimation method of heat capacities.  相似文献   

Aragonite from Mulanshan Glaucophane Schist: Implications for Regional Evolution of Southwestern Dabie Mountains, Central China     

Zhao Wenyu Center of Material Research  Analysis  Wuhan University of Technology  Wuhan Liu Rong Wang QinyanFaculty of Earth Sciences  China University of Geosciences  Wuhan Peng Changqi Zhang QingjieCenter of Material Research  Anal 《中国地质大学学报(英文版)》2001,12(3)

ＩＮＴＲＯＤＵＣＴＩＯＮＩｔｉｓａｎａｃｋｎｏｗｌｅｄｇｅｄｆａｃｔｔｈａｔａｒａｇｏｎｉｔｅ,ａｈｉｇｈ ｐｒｅｓｓｕｒｅｐｏｌｙｍｏｒｐｈｏｆＣａＣＯ3 ,ｏｃｃｕｒｓｗｉｄｅｌｙａｓａｎｉｎｄｅｘｍｉｎｅｒａｌｏｆｈｉｇｈ ｐｒｅｓｓｕｒｅａｎｄｌｏｗ ｔｅｍｐｅｒａｔｕｒｅｍｅｔａｍｏｒｐｈｉｓｍ (ｇｌａｕｃｏｐｈａｎｅｓｃｈｉｓｔｆａｃｉｅｓ)ｗｉｔｈｉｎｔｈｅｇｅｏｄｙｎａｍｉｃｃｏｎｔｅｘｔｏｆｓｕｂｄｕｃｔｉｏｎ ｏｂｄｕｃｔｉｏｎａｎｄｃｏｎｔｉｎｅｎｔａｌｃｏｌｌｉｓｉｏｎ (Ｌｉｏｕ…  相似文献   

陕北鄂尔多斯盆地埋藏变质作用研究   总被引：11，自引：2，他引：11  

张立飞 《地质学报》1992,66(4):339-349

本文系统地研究了陕北鄂尔多斯盆地的埋藏变质作用。砂岩胶结物在成岩到变质作用转化过程中经历了如下4个阶段:1.粘土胶结阶段;2.压溶长石、石英再生长阶段;3.碳酸盐胶结阶段;4.生成浊沸石阶段。泥岩中粘土矿物组合在埋藏变质过程中出现如下转化:早期蒙皂石、高岭石组合,随埋深的增加转化为伊利石和镁铝蛇纹石混合阶段;进一步埋深出现了伊利石和绿泥石混层阶段;最后转化为分散状的伊利石和绿泥石。  相似文献   

EXTRACTION OF THE STANDARD ENTHALPY OF FORMATION OF MINERALS FROM REVERSED EXPERIMENTAL DATA WITH INS     

Yin Huian Han Wenxi Lu Cheng Wang Yunliang 《矿物岩石》1992,(4)

An improvement on the new method of Intervalhalving-Scanning (INS) proposed by the senior author for derivation of thermodynamic properties of minerals from reversed experiment (REP) data has been made in the present work. The treatment of the REP data of 6 reactions in the system MgO-SiO_2-H_2O and the derivation of △_(?)H(?) (298. 15K) for minerals Talc,Forsterite and Anthophyllite are chosen as an example for demonstration of the application of the method.INS is quite different from all the methods for the derivation in the literature and throughout based on thermodynamic principles and equations so that its thermodynamical validity is thoroughgoing.  相似文献   

我国一些铜镍硫化物矿床主要金属矿物的特征   总被引：7，自引：0，他引：7  

陈殿芬 《岩石矿物学杂志》1995,14(4):345-354

镍、铜共生的铜镍硫化物矿床是镍矿也是铜矿的重要矿床类型。磁黄铁矿，镍黄铁矿、黄铜矿是这类矿床的主要金属矿物。它们的某些矿物学特征，特别是微量元素Ｃｏ／Ｎｉ比值，与其他铜矿类型明显不同，这三种矿物组成不同于任何其他铜矿类型的典型矿物共生组合， 形成特殊的海绵损铁状、球滴状构造。  相似文献